Friday, May 8, 2009

Lattice Energy : Part I and II

Lattice Energy, ∆HΘlat.

∆HΘlat. is the energy released when 1 mol of an ionic compound in the solid state is formed from its gaseous ions under standard conditions.

Na+(g) + Cl-(g) → NaCl(s) ∆HΘlat.= -788 kJ mol-1.

Magnitude of lattice energy is proportional to the charge on the ion and is inversely proportional to the interionic distance (r+ + r-) .


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